Adding a small amount of vinegar at the start can help prevent mold growth during fermentation, but excessive amounts can inhibit the beneficial bacteria and hinder the fermentation process.
Vinegar, specifically acetic acid, acts as a natural preservative. It lowers the pH of the fermentation environment, making it less hospitable for mold and other undesirable microorganisms to thrive. Mold generally prefers a neutral to slightly alkaline environment. By introducing a small amount of vinegar, you create a more acidic environment that favors the growth of beneficial bacteria, such as lactic acid bacteria, which are crucial for many fermentation processes like sauerkraut or kimchi. However, it's a delicate balance. Too much vinegar can significantly lower the pH, inhibiting the growth of even the beneficial bacteria, thus slowing down or even stopping the fermentation process altogether. The ideal amount of vinegar depends on the specific fermentation project, the ingredients used, and the desired outcome. It's best to start with a very small amount and monitor the fermentation closely. For example, when fermenting vegetables, a tablespoon or two of vinegar per quart jar is often sufficient.
Always use distilled white vinegar or apple cider vinegar for fermentation, as other types of vinegar may contain additives or flavorings that can negatively impact the fermentation process or introduce unwanted microorganisms.