Yes, vegetables can be over-fermented. Over-fermented vegetables will often be mushy, have an unpleasant, overly acidic or alcoholic taste, and may develop mold or other undesirable microbial growth.
Fermentation is a process where microorganisms, like bacteria and yeast, convert carbohydrates into acids, gases, or alcohol. In vegetable fermentation, lactic acid bacteria (LAB) are the primary actors, producing lactic acid which preserves the vegetables and gives them their characteristic tangy flavor. However, if fermentation goes on for too long, several things can happen:
Excessive Acid Production: LAB continue to produce acid, leading to a very sour or acidic taste that is unpalatable. The pH can drop too low, inhibiting the growth of beneficial bacteria and potentially favoring undesirable microorganisms.
Softening of Texture: Enzymes produced by the microorganisms can break down the pectin in the vegetables, leading to a mushy or slimy texture. This is especially noticeable in vegetables with high pectin content, like cucumbers or carrots.
Development of Off-Flavors: While some flavor changes are desirable during fermentation, over-fermentation can lead to the production of undesirable compounds, resulting in off-flavors or an alcoholic taste. This can be due to the activity of yeasts or other bacteria that thrive in the acidic environment.
Mold Growth: While not always a sign of over-fermentation, mold growth can occur if the fermentation environment is not properly maintained or if the vegetables are exposed to air. This is more likely in over-fermented vegetables as the protective effects of the initial fermentation process diminish.
Visually, over-fermented vegetables might appear darker, softer, or have a slimy coating. The brine might be cloudy or have sediment at the bottom. The smell will be intensely sour or even putrid.
To prevent over-fermentation, regularly taste your fermenting vegetables. Start tasting after a few days and refrigerate them when they reach your desired level of sourness. Refrigeration significantly slows down the fermentation process.