Using room temperature ingredients, especially eggs, is crucial for making mayonnaise because it helps create a stable emulsion, preventing the mayonnaise from separating. Room temperature ingredients blend more easily and evenly.
The success of mayonnaise hinges on creating a stable emulsion, which is a mixture of two liquids that don't normally mix (like oil and water/vinegar). Eggs act as an emulsifier, binding the oil and vinegar together. When ingredients are cold, several things can go wrong:
Poor Emulsification: Cold eggs don't emulsify as readily as room temperature eggs. The proteins in the egg yolk are less flexible and don't bind as effectively with the oil and vinegar.
Separation: The rapid temperature change when cold ingredients are combined can shock the emulsion, causing it to break and separate. The oil will separate from the vinegar and egg mixture, resulting in a thin, unusable mayonnaise.
Uneven Blending: Cold oil is more viscous and harder to incorporate smoothly into the mixture. This can lead to pockets of oil that haven't been properly emulsified, increasing the risk of separation.
Bringing the eggs, oil, and vinegar to room temperature allows for a smoother, more stable emulsion, resulting in a creamy, consistent mayonnaise.
If your mayonnaise starts to separate, try whisking a tablespoon of warm water into a separate bowl, then slowly drizzling the separated mayonnaise into the water while whisking constantly. This can sometimes re-emulsify the mixture.