The acid in a vinaigrette tenderizes vegetables and fruits by breaking down their cell structure, and it also inhibits enzymatic browning, preserving their color. The acid also adds a tangy flavor.
When vegetables or fruits marinate in a vinaigrette, the acid, typically vinegar or citrus juice, plays several key roles. First, it begins to break down the cell walls of the plant matter. This process, similar to a very mild form of cooking, tenderizes the vegetables or fruits, making them easier to chew and digest. The extent of this tenderization depends on the strength of the acid and the duration of the marination.
Second, the acid inhibits enzymatic browning. Many fruits and vegetables contain enzymes that react with oxygen when cut, causing them to turn brown. The acid in the vinaigrette lowers the pH, which slows down or stops the activity of these enzymes, helping to preserve the vibrant color of the marinated ingredients. This is why lemon juice is often used on cut apples or avocados.
Finally, the acid contributes significantly to the flavor profile. It adds a tangy, bright taste that complements the natural sweetness of fruits and the savory notes of vegetables. The acid balances the richness of the oil in the vinaigrette and enhances the overall taste of the dish.
Avoid marinating delicate leafy greens in vinaigrette for extended periods, as the acid can cause them to wilt and become soggy. Add the vinaigrette just before serving for the best texture.