Vinegar-based chutney discolors primarily due to oxidation of the ingredients, especially fruits and vegetables, and reactions between acids in the vinegar and certain compounds in the spices or produce.
The discoloration of vinegar-based chutney is a common issue that arises from several chemical processes. Here's a breakdown:
Oxidation: When fruits and vegetables are exposed to air, enzymes cause them to brown. This enzymatic browning is a form of oxidation. While the vinegar helps to slow this process, it doesn't eliminate it entirely, especially if the chutney isn't stored properly.
Maillard Reaction: This is a chemical reaction between amino acids and reducing sugars that requires heat. While chutney isn't typically cooked at high temperatures for long periods, some Maillard reaction can still occur, contributing to browning over time.
Reactions with Metals: Certain metals, like iron or copper, can react with the acids in vinegar and the compounds in the chutney ingredients, leading to discoloration. Using reactive cookware or utensils can accelerate this process.
Spice Interactions: Some spices contain compounds that can react with the acids in vinegar or with other ingredients, leading to color changes. For example, certain spices might darken or fade over time.
Light Exposure: Exposure to light can also contribute to discoloration by accelerating oxidation and other chemical reactions.
To minimize discoloration, store your vinegar-based chutney in an airtight container in a cool, dark place. Adding a small amount of ascorbic acid (vitamin C) or citric acid can also help to inhibit oxidation and preserve the color.