Mint blackens when blended with water due to the oxidation of phenolic compounds present in the mint leaves, accelerated by the blending process which releases enzymes and increases surface area exposure to oxygen. Adding an acid like lemon juice can help prevent this.
The blackening of mint when blended with water is primarily due to a chemical reaction called enzymatic browning. Mint leaves contain phenolic compounds, which are naturally colorless. When the mint leaves are blended, the cell structure is disrupted, releasing enzymes called polyphenol oxidases (PPO). These enzymes catalyze the oxidation of the phenolic compounds in the presence of oxygen. This oxidation process converts the colorless phenolic compounds into quinones, which then polymerize to form melanins, dark-colored pigments that cause the blackening. The blending process also increases the surface area of the mint exposed to oxygen, further accelerating the reaction. The water itself doesn't directly cause the blackening, but it provides a medium for the enzymes and phenolic compounds to interact, and it facilitates the oxidation process.
To prevent mint from blackening when blending, add a small amount of an acid, such as lemon juice or lime juice, to the mixture. The acid lowers the pH, inhibiting the activity of the polyphenol oxidase enzymes and slowing down the browning process.