Roasted cumin powder smells smoky over time because the volatile aromatic compounds responsible for its fresh, bright flavor degrade and oxidize, leaving behind the deeper, more roasted notes. This process is accelerated by exposure to air, light, and heat.
Cumin's distinctive aroma comes from a complex blend of volatile organic compounds, including cuminaldehyde, cymene, and beta-pinene. Roasting cumin enhances these flavors by initiating Maillard reactions and caramelization, creating a richer, more complex profile. However, these compounds are also susceptible to degradation.
Over time, especially when exposed to air, light, and heat, these volatile compounds oxidize and evaporate. The lighter, brighter notes diminish, leaving behind the heavier, more stable compounds that contribute to the smoky or earthy aroma. Think of it like the top notes of a perfume fading, leaving only the base notes. The oxidation process also creates new compounds that can contribute to the altered smell. Improper storage accelerates this process significantly.
To preserve the fresh aroma of roasted cumin powder, store it in an airtight container in a cool, dark place. Consider roasting whole cumin seeds in small batches as needed and grinding them just before use for the most vibrant flavor.