Tamarind pulp darkens after refrigeration due to enzymatic browning and oxidation, processes accelerated by the cold temperature and exposure to air. These reactions alter the pigments in the tamarind, leading to a darker color.
Tamarind pulp contains enzymes that, when exposed to oxygen, cause browning. Refrigeration, while slowing down microbial growth, doesn't completely halt these enzymatic reactions. The cold temperature can actually disrupt cell structures, releasing more enzymes and accelerating the browning process. Additionally, oxidation occurs when the tamarind pulp interacts with air. The compounds in tamarind react with oxygen, leading to a change in color. The longer the tamarind is stored, and the more it's exposed to air, the darker it will become. The natural sugars and acids in tamarind also contribute to this darkening effect over time.
To minimize darkening, store tamarind pulp in an airtight container in the refrigerator. You can also add a small amount of lemon juice or ascorbic acid (Vitamin C) as a natural antioxidant to help prevent browning.