Froth on top of stored chutney is usually caused by fermentation, where microorganisms like yeast or bacteria consume sugars in the chutney and produce carbon dioxide gas as a byproduct. This gas creates bubbles, resulting in the frothy appearance.
Chutneys, especially those made with fruits or vegetables, contain natural sugars. Even with preservatives like vinegar, salt, or sugar, some microorganisms can survive and thrive, particularly if the chutney wasn't properly sterilized during preparation or if the storage conditions aren't ideal. These microorganisms, often yeasts or bacteria, break down the sugars through fermentation. This process generates carbon dioxide (CO2) and other byproducts. The CO2 gets trapped within the chutney, forming bubbles that rise to the surface, creating the froth you observe. The presence of froth indicates that the chutney is undergoing spoilage and its flavor and safety may be compromised. Factors that contribute to this include insufficient acidity, inadequate sterilization of jars and utensils, improper sealing, and storage at warm temperatures.
To prevent froth formation, ensure your chutney has a high enough acidity level (add more vinegar or lemon juice), thoroughly sterilize jars and lids before filling, and process the filled jars in a boiling water bath for the recommended time to create a proper seal. Store the chutney in a cool, dark place after processing.