Chefs add zest at the end of cooking to preserve its volatile oils, which contain the most intense citrus flavor and aroma, preventing them from dissipating in the heat.
Citrus zest contains essential oils that are responsible for its bright, fresh flavor and aroma. These oils are highly volatile, meaning they evaporate easily, especially when exposed to heat. If zest is added early in the cooking process, the heat will cause these oils to dissipate, resulting in a significantly diminished flavor. By adding zest at the very end, just before serving, you ensure that these oils are preserved, delivering the maximum citrus punch to the dish. This technique allows the zest's vibrant flavor to shine through, enhancing the overall taste experience. The heat from the cooked dish will gently warm the zest, releasing its aroma without cooking away the essential oils.
Use a microplane grater to zest citrus fruits. This tool produces fine, feathery zest that incorporates easily into dishes and releases its flavor more readily than larger zest pieces. Avoid grating the white pith underneath the colored zest, as it can be bitter.