Fresh zest has a vibrant, intense citrus flavor due to the volatile oils. As zest sits, these oils evaporate, leading to a significant loss of flavor and aroma.
The zest of citrus fruits, like lemons, limes, and oranges, contains concentrated flavor compounds found in the outer layer of the peel. These compounds are primarily volatile oils, which are responsible for the bright, characteristic aroma and taste. When you zest a citrus fruit, you're releasing these oils.
Immediately after zesting, the flavor is at its peak. The oils are fresh and haven't had time to dissipate. However, these oils are sensitive to air, light, and heat. As the zest sits exposed to these elements, the volatile oils begin to evaporate. This process is called oxidation, and it leads to a gradual decline in the zest's flavor intensity.
Older zest will have a noticeably weaker flavor compared to freshly grated zest. It may also develop a slightly bitter or stale taste as the oils degrade. The aroma will also be significantly diminished. Therefore, for the best flavor in your recipes, it's always recommended to use zest as soon as possible after grating it.
To preserve zest for a short period, mix it with sugar. The sugar helps to absorb some of the oils and protect them from evaporation. Store the sugar-zest mixture in an airtight container in the refrigerator. This will help retain more flavor than storing the zest alone.