Citrus zest contains volatile oils that contribute significantly to its flavor and aroma. These oils dissipate quickly after zesting, so zesting right before use ensures the most potent and fresh citrus flavor in your dish.
The zest of citrus fruits, like lemons, limes, oranges, and grapefruits, is the outermost layer of the peel, rich in essential oils. These oils are responsible for the characteristic bright, citrusy aroma and flavor. When you zest a citrus fruit, you're releasing these oils. However, these oils are volatile, meaning they evaporate easily when exposed to air and light.
Over time, the exposed oils oxidize and degrade, leading to a significant loss of flavor and aroma. Zesting immediately before use minimizes the time these oils are exposed to the elements, preserving their potency. This results in a much more vibrant and noticeable citrus flavor in your recipe. Think of it like freshly ground spices versus pre-ground – the difference in aroma and taste is significant.
Furthermore, the zest also contains enzymes that can react with the air and cause the zest to become bitter over time. Using it immediately reduces the chance of this bitterness developing.
When zesting, avoid grating too deeply into the white pith beneath the colored zest. The pith is bitter and will negatively impact the flavor of your dish. Use a microplane or a zester that only removes the outer layer of the peel.