Zesting releases aromatic oils from the citrus fruit's peel by rupturing the oil cells, enhancing flavor and aroma in cooking. The zest contains concentrated oils that are otherwise locked within the rind.
Zesting involves scraping or grating the outer layer of citrus fruit peels, such as lemons, limes, oranges, or grapefruits. This outer layer, called the zest, is rich in essential oils. These oils are contained within tiny sacs or cells in the peel. When you zest, you're essentially breaking open these cells, releasing the oils. These oils are highly aromatic and flavorful, contributing significantly to the overall taste and smell of a dish. The act of grating or scraping physically ruptures the oil-containing cells, allowing the volatile aromatic compounds to escape and infuse the dish with their characteristic citrusy notes. The finer the zest, the more cells are ruptured, and the more intense the flavor release. The white pith underneath the zest is bitter and should be avoided, as it doesn't contain the desirable oils.
Use a microplane zester for the finest zest and maximum oil release. Avoid pressing too hard, which can include the bitter white pith.