Yes, adding mustard to mayonnaise can help emulsification due to mustard's natural emulsifying properties. You can use different types of mustard, but Dijon mustard is often preferred for its strong emulsifying capabilities and flavor.
Mustard contains compounds, including mucilage, that act as natural emulsifiers. Emulsifiers help to stabilize mixtures of oil and water, preventing them from separating. Mayonnaise is an emulsion of oil, egg yolks (which also act as emulsifiers), and an acid like vinegar or lemon juice. Adding mustard can further enhance the stability of the emulsion, especially if you're making mayonnaise from scratch or trying to revive a slightly broken mayonnaise.
Different types of mustard will have varying degrees of emulsifying power and will also impart different flavors. Dijon mustard is a popular choice because it contains a higher concentration of mucilage and has a relatively neutral flavor that complements many dishes. Other mustards, such as whole-grain mustard or spicy brown mustard, can also be used, but they may affect the final flavor profile more noticeably. Experiment to find the mustard that best suits your taste preferences.
Here's how to incorporate mustard into mayonnaise:
If your mayonnaise is already separating, whisk in a teaspoon of mustard along with a tablespoon of warm water. The mustard will help re-emulsify the mixture, and the warm water will aid in the process. Whisk vigorously until the mayonnaise comes back together.