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Why does your vinaigrette often separate? Discover the science behind emulsions and learn simple tricks to keep your dressing emulsified longer.
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Vinaigrette separates because oil and vinegar are immiscible; they don't naturally mix. To keep it emulsified longer, use a strong emulsifier like mustard or honey, and whisk vigorously or use a blender.

Detailed Explanation:

Vinaigrette is a temporary emulsion, meaning it's a mixture of two liquids that don't naturally stay combined. In this case, it's oil and vinegar. Oil is hydrophobic (repels water) and vinegar is water-based, so they tend to separate over time.

To create a stable vinaigrette, you need an emulsifier. An emulsifier is a substance that helps to bind the oil and vinegar together. Common emulsifiers include:

  1. Mustard: Dijon mustard is a particularly effective emulsifier due to its lecithin content.

  2. Honey or Maple Syrup: The sugars help to thicken the vinaigrette and stabilize the emulsion.

  3. Egg Yolk: Used in more decadent vinaigrettes, egg yolk provides a strong and stable emulsion.

  4. Garlic or Shallots (finely minced): These can add flavor and contribute slightly to emulsification.

The process of emulsification involves dispersing one liquid (the oil) as tiny droplets within the other liquid (the vinegar). This requires energy, which is why vigorous whisking or blending is necessary. Start by whisking the emulsifier with the vinegar, then slowly drizzle in the oil while continuing to whisk constantly. This creates a stable emulsion.

Pro Tip:

Use a blender or immersion blender for a longer-lasting emulsion. The high speed of the blades creates much smaller oil droplets, resulting in a more stable and less likely to separate vinaigrette.

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