Mustard oil solidifies in winter due to its high concentration of saturated fatty acids, which have higher melting points and solidify at lower temperatures. The specific temperature at which it solidifies depends on the exact composition of the oil.
Mustard oil is composed of various fatty acids, including both saturated and unsaturated fats. Saturated fatty acids have a linear structure, allowing them to pack closely together. This close packing results in stronger intermolecular forces, leading to a higher melting point. When the temperature drops in winter, the kinetic energy of the molecules decreases. This allows the intermolecular forces between the saturated fatty acids to dominate, causing them to arrange into a more ordered, solid structure. The higher the proportion of saturated fats in the mustard oil, the higher its solidification temperature will be. Unsaturated fatty acids, on the other hand, have kinks in their structure due to the presence of double bonds. These kinks prevent them from packing as closely, resulting in weaker intermolecular forces and lower melting points. Therefore, oils with a higher proportion of unsaturated fats tend to remain liquid at lower temperatures. The exact temperature at which mustard oil solidifies can vary depending on its specific fatty acid composition, but it generally occurs at temperatures below 10-15°C (50-59°F).
To liquefy solidified mustard oil quickly, gently warm it in a water bath or microwave it in short intervals, stirring frequently to ensure even heating and prevent overheating.