Pickles develop a film on the surface due to the growth of harmless yeasts that thrive in the brine solution. These yeasts consume sugars and produce byproducts that form the visible film.
The film that appears on the surface of pickles is usually a type of yeast or mold that is naturally present in the environment. These microorganisms are often airborne and can enter the pickle jar even after it has been opened. The brine solution, which is typically a mixture of water, salt, and vinegar, provides a suitable environment for these yeasts to grow, especially if there are residual sugars present from the pickling process or the vegetables themselves. As the yeasts metabolize these sugars, they produce byproducts, including carbon dioxide and other compounds, which contribute to the formation of the film. This film is generally harmless and doesn't necessarily mean the pickles are spoiled, but it can affect the flavor and texture of the brine. The presence of the film indicates that the fermentation process may still be active, or that the pickles were not properly sealed or stored.
To minimize film formation, ensure your pickle jars are properly sealed and refrigerated after opening. Adding a thin layer of olive oil to the surface of the brine can also help create a barrier against air and reduce yeast growth.