Mint oil solidifies in cool temperatures due to the crystallization of menthol, its primary component, which has a relatively high melting point. This is a natural process and doesn't affect the oil's quality.
Mint oil is primarily composed of menthol, a cyclic alcohol that gives mint its characteristic cooling sensation and aroma. Menthol has a melting point that is significantly higher than room temperature, typically around 21-23°C (70-73°F). When mint oil is exposed to temperatures below this range, the menthol molecules begin to lose kinetic energy and arrange themselves into a crystalline structure. This crystallization process causes the oil to thicken and eventually solidify. The degree of solidification depends on the concentration of menthol in the oil and the temperature to which it is exposed. Other components of mint oil, such as menthone and other terpenes, may also contribute to the solidification process, but menthol is the primary driver. The solidification is a physical change, not a chemical one, and the oil will return to its liquid state when warmed.
If your mint oil solidifies, gently warm the bottle in a warm water bath (not boiling) to return it to its liquid state. Avoid using a microwave, as this can damage the oil's delicate aroma and properties.