Freezing yogurt causes the water content to form ice crystals, which disrupt the protein structure. Upon thawing, the whey separates from the solids, resulting in a grainy or watery texture.
Yogurt's smooth and creamy texture is due to a delicate network of proteins, primarily casein, that are stabilized by the water content. When yogurt is frozen, the water molecules expand and form ice crystals. These ice crystals physically damage the protein network, causing it to break down.
Upon thawing, the damaged protein structure is unable to hold the water as effectively as before. This leads to the separation of the whey (the watery part) from the solid curds. The result is a yogurt that appears grainy, watery, and less appealing than its original state. The extent of separation depends on factors like the type of yogurt (Greek yogurt tends to separate less due to its higher protein content) and the freezing/thawing process. Slow freezing and thawing can exacerbate the separation.
To minimize separation, stir the yogurt thoroughly after thawing. While it won't completely restore the original texture, it can help reincorporate some of the whey and improve the overall consistency. Consider using thawed yogurt in smoothies or baked goods where the texture change is less noticeable.