Butter develops brown patches when stored improperly due to oxidation and exposure to light and air, which cause the surface fats to degrade and discolor.
Butter is primarily composed of fat, water, and milk solids. When butter is exposed to light, air, and fluctuating temperatures, several processes contribute to the formation of brown patches. First, oxidation occurs, where the fats in the butter react with oxygen in the air. This reaction leads to rancidity and the breakdown of fatty acids, resulting in off-flavors and discoloration. Second, light can catalyze these oxidation reactions, accelerating the degradation process. Third, temperature fluctuations can cause the butter to melt and re-solidify, leading to the separation of water and fat. This separation creates an uneven surface that is more susceptible to oxidation and discoloration. The milk solids present in butter can also darken when exposed to air and light, contributing to the brown patches. Proper storage minimizes these effects by reducing exposure to these elements.
To prevent brown patches, store butter in an airtight container in the refrigerator, preferably in the coldest part away from the door. Consider wrapping the butter tightly in parchment paper or foil before placing it in the container for added protection against light and air.