Adding a pinch of baking soda (sodium bicarbonate) to an overly acidic dish neutralizes the acid, raising the pH and making it less sour. It's appropriate when the acidity is overpowering and you want to balance the flavors, but use it sparingly to avoid a soapy taste.
Baking soda is a base, meaning it has a high pH. When you add it to an acidic dish, a chemical reaction occurs. The sodium bicarbonate reacts with the acid (like citric acid in tomatoes or acetic acid in vinegar) to produce carbon dioxide, water, and a salt. The carbon dioxide is released as bubbles, which you might see when you add baking soda to a sauce. The water dilutes the mixture slightly, and the salt remains in the dish. The overall effect is a reduction in acidity and a more balanced flavor profile. This is particularly useful in tomato-based sauces, soups, or stews that have become too tart. However, it's crucial to add baking soda in very small increments, tasting as you go, because too much can impart a soapy or metallic taste. The amount needed depends on the acidity level of the dish and the overall volume. Start with just a pinch (1/8 teaspoon or less) for a large pot of sauce and stir well to ensure it's evenly distributed.
If you accidentally add too much baking soda and notice a soapy taste, try adding a small amount of an acidic ingredient like lemon juice or vinegar to counteract the excess baking soda. This can help restore the flavor balance, but be careful not to overdo it and make the dish acidic again.