Chilled ingredients, especially vegetables and meats, are generally easier to dice cleanly because they are firmer and less likely to slip or squish under the knife. Room temperature ingredients tend to be softer and more pliable, making precise dicing more challenging.
The temperature of an ingredient significantly impacts its structural integrity, which directly affects how easily it can be diced. When an ingredient is chilled, the water within its cells freezes or becomes very cold, causing the cells to become more rigid. This rigidity provides resistance against the knife, allowing for cleaner, more uniform cuts. Think of dicing a chilled potato versus a room temperature one; the chilled potato will hold its shape better and produce more consistent dice.
Conversely, room temperature ingredients are generally softer and more flexible. This is because the cellular structure is more relaxed, and the ingredient yields more easily to pressure. While this might be desirable for some cooking applications, it makes dicing more difficult. The ingredient is more likely to squish, slip, or tear, resulting in uneven and messy dice. For example, a room temperature tomato is much harder to dice neatly than a slightly chilled one. The same principle applies to meats; slightly frozen meat is much easier to slice thinly or dice than fully thawed meat.
For ingredients that are naturally soft or prone to slipping, such as onions, try chilling them in the freezer for 10-15 minutes before dicing. This will firm them up slightly and make the process much easier, while also reducing the amount of eye-watering fumes released.