Chopping vegetables increases their surface area, leading to greater moisture release during cooking due to cell damage and easier evaporation.
When you chop vegetables, you're essentially breaking down their cell walls. These cell walls contain water and other fluids. The smaller the pieces you chop, the more cells you damage, and the more surface area you create. This increased surface area allows more moisture to escape from the damaged cells. Think of it like this: a whole potato has a relatively small surface area exposed to heat. A diced potato has significantly more surface area exposed, allowing water to evaporate more readily. This is why chopped vegetables often release more water into the pan during cooking compared to whole or larger pieces. The heat applied during cooking further accelerates this process, causing the cell walls to weaken and release their contents.
If you want to minimize moisture release, especially when sautéing, try to use larger pieces of vegetables or cook them at a higher heat to quickly evaporate the released moisture before it accumulates in the pan.