Black mustard seeds pop and splutter in hot oil due to the moisture inside them rapidly turning to steam, causing the seed coat to rupture. This is a key characteristic that releases their pungent flavor.
Black mustard seeds contain a small amount of moisture within their outer shell. When these seeds are added to hot oil, the heat causes this moisture to quickly vaporize and turn into steam. Because the seed coat is relatively impermeable, the pressure from the rapidly expanding steam builds up inside. Eventually, this pressure exceeds the strength of the seed coat, causing it to rupture explosively. This rupture is what we perceive as the 'popping' or 'spluttering' sound. This process is crucial for releasing the characteristic pungent and nutty flavor of the mustard seeds, as it breaks down compounds within the seed and allows them to interact with the hot oil. The heat also helps to temper the bitterness of the seeds, resulting in a more palatable and complex flavor profile. The popping is a sign that the seeds are properly tempered and ready to impart their flavor to the dish.
To prevent mustard seeds from splattering excessively and potentially burning you, always use a lid or splatter screen when tempering them in hot oil. This will contain the popping seeds and ensure even cooking.