Sautéed onions have a mild, slightly sweet flavor, while caramelized onions are deeply sweet, rich, and complex due to the breakdown of sugars during a longer cooking process.
The difference in flavor between sautéed and caramelized onions comes down to the cooking time and the chemical reactions that occur. Sautéing involves cooking onions over medium heat for a shorter period, typically until they become translucent and slightly softened. This process releases some of the onion's natural sugars, resulting in a mild sweetness.
Caramelization, on the other hand, is a much slower process. Onions are cooked over low heat for a longer duration, often 30-45 minutes or more. This extended cooking time allows the natural sugars in the onions to break down and undergo a Maillard reaction, creating hundreds of new flavor compounds. The result is a deep, rich, and complex sweetness with notes of butterscotch and roasted vegetables. The onions also become significantly softer and develop a dark brown color.
Don't overcrowd the pan when caramelizing onions. Overcrowding steams the onions instead of browning them. Cook in batches if necessary to ensure even caramelization.