Onions take longer to brown in non-stick pans because the non-stick coating inhibits the Maillard reaction, which is responsible for browning, and also reduces direct contact between the onions and the hot pan surface.
Browning, also known as the Maillard reaction, is a chemical process that occurs between amino acids and reducing sugars, giving browned food its distinctive flavor. This reaction requires high heat and direct contact with the cooking surface. Non-stick pans, while excellent for preventing food from sticking, have a coating that acts as a barrier. This barrier reduces the direct transfer of heat to the onions and interferes with the Maillard reaction. Additionally, the non-stick surface often prevents the natural sugars released by the onions from caramelizing effectively, further slowing down the browning process. The onions essentially steam in their own moisture for a longer period before they begin to brown. Using a higher heat setting can help, but it also increases the risk of burning the onions before they fully caramelize.
To help onions brown faster in a non-stick pan, avoid overcrowding the pan. Overcrowding lowers the pan's temperature and increases moisture, hindering browning. Cook the onions in smaller batches or use a larger pan to ensure they have enough space to make direct contact with the pan's surface.