Onions develop a metallic taste when overcooked due to the breakdown of sulfur compounds, which then react with metals in your cookware or even naturally present in the onion itself. This reaction creates volatile compounds that our taste buds perceive as metallic.
Onions contain sulfur compounds that are released when they are cut or cooked. These compounds are responsible for the onion's characteristic flavor and aroma. When onions are cooked for an extended period, especially at high temperatures, these sulfur compounds break down further. Some of these breakdown products can react with metal ions, such as iron or copper, present in your cooking pan or even naturally occurring in the onion. This reaction forms volatile compounds, like sulfites and other sulfur-containing molecules, that have a metallic taste. The longer the onions cook, and the higher the heat, the more pronounced this metallic taste becomes. Additionally, using acidic ingredients like tomatoes or vinegar can exacerbate the reaction, as they can help to release more of the sulfur compounds.
To prevent a metallic taste, avoid overcooking onions, especially in reactive cookware like uncoated cast iron or aluminum. Use stainless steel or enamel-coated pots and pans, and consider adding acidic ingredients towards the end of the cooking process.