Dairy products, like milk, yogurt, or cheese, contain fats and proteins that bind to spicy compounds, effectively neutralizing them and reducing the sensation of heat. This creates a more balanced and palatable flavor profile.
The burning sensation we experience from spicy foods comes primarily from a compound called capsaicin, found in chili peppers. Capsaicin is non-polar, meaning it dissolves in fats and oils rather than water. Dairy products are rich in fats and a protein called casein. When you consume dairy with spicy food, the capsaicin molecules bind to these fats and casein proteins. This binding action prevents the capsaicin from reaching the pain receptors in your mouth and throat, thus reducing the perceived heat. The fat coats the mouth, providing a physical barrier, while the casein actively captures and neutralizes the spicy compounds. Different dairy products have varying levels of fat and protein, so their effectiveness in reducing spice can differ. For example, whole milk or full-fat yogurt will generally be more effective than skim milk.
If you accidentally over-spice a dish, adding a dollop of sour cream or a splash of coconut milk (which is high in fat) can often salvage it by mellowing out the heat. Start with a small amount and taste as you go to avoid diluting the other flavors too much.